Some really great picks here for sure
A More Perfect Union-Titus Andronicus
Literally any Laura Stevenson opener
Fear and Trembling-Gang of Youths
Fake Empire-The National
You Ain't Worth A Dollar (Queens of the Stone Age) is a great one. Belt by Say Anything is one of my favorite album openers too. The brief meta spoken word part straight into the riff gets me every time.